Thermo-Calc / DICTRA Only for use at 10120 Local contact Ruhr-Universitat Bochum, Inst. fur Werkstoffe Lehrstuhl Werkstofftechnik M.Sc. Janis Kimm Lic-100230-NWL 99 SYS:go data THERMODYNAMIC DATABASE module Database folder: C:\Program Files\Thermo-Calc\2024a\data Current database: Steels/Fe-Alloys v10.1 VA /- DEFINED DICTRA_FCC_A1 REJECTED TDB_TCFE10:sw ssol4 Current database: SGTE Alloy Solutions v4.9g VA DEFINED FCC_L102 FCC_L12 REJECTED ALNI_B2 A2_BCC BCC_B2 REJECTED GAS:G REJECTED IONIC_LIQUID:Y BI2O3_LIQUID:Y CORUNDUM:I REJECTED *** WARNING: This database cannot be used with GES6, temporarily reverting to G ES5 TDB_SSOL4:def_el al si mg mn AL SI MG MN DEFINED TDB_SSOL4:get REINITIATING GES ..... ELEMENTS ..... SPECIES ...... PHASES ....... PARAMETERS ... FUNCTIONS .... List of references for assessed data 'SSOL4.9 (2004-2008): The SGTE General Alloy Solutions Database, V4.9f, developed by SGTE (Scientific Group Thermodata Europe), and provided by Thermo-Calc Software. ' -OK- TDB_SSOL4:go poly POLY version 3.32 POLY:s-c n=1 p=1e5 T=850 POLY:s-c w(si)=0.007 w(mg)=0.006 w(mn)=0.004 POLY:l-c N=1, P=100000, T=850, W(SI)=7E-3, W(MG)=6E-3, W(MN)=4E-3 DEGREES OF FREEDOM 0 POLY:c-e Using global minimization procedure Calculated 30111 grid points in 0 s Found the set of lowest grid points in 0 s Calculated POLY solution 0 s, total time 0 s POLY:l-e OUTPUT TO SCREEN OR FILE /SCREEN/: Options /VWCS/: Output from POLY-3, equilibrium = 1, label A0 , database: SSOL4 Conditions: N=1, P=100000, T=850, W(SI)=7E-3, W(MG)=6E-3, W(MN)=4E-3 DEGREES OF FREEDOM 0 Temperature 850.00 K ( 576.85 C), Pressure 1.000000E+05 Number of moles of components 1.00000E+00, Mass in grams 2.70266E+01 Total Gibbs energy -3.34532E+04, Enthalpy 1.54944E+04, Volume 0.00000E+00 Component Moles W-Fraction Activity Potential Ref.stat AL 9.8462E-01 9.8300E-01 9.2951E-03 -3.3063E+04 SER MG 6.6719E-03 6.0000E-03 8.4975E-05 -6.6243E+04 SER MN 1.9678E-03 4.0000E-03 1.3541E-08 -1.2804E+05 SER SI 6.7362E-03 7.0000E-03 1.3543E-02 -3.0403E+04 SER FCC_A1 Status ENTERED Driving force 0.0000E+00 Moles 9.9187E-01, Mass 2.6767E+01, Volume fraction 0.0000E+00 Mass fractions: AL 9.86771E-01 MG 6.05828E-03 SI 6.03435E-03 MN 1.13676E-03 ALMNSI_ALPHA Status ENTERED Driving force 0.0000E+00 Moles 8.1302E-03, Mass 2.5998E-01, Volume fraction 0.0000E+00 Mass fractions: AL 5.94796E-01 MN 2.98786E-01 SI 1.06418E-01 MG 0.00000E+00 POLY:s-c T=973 POLY:c-e Using global minimization procedure Calculated 30111 grid points in 0 s Found the set of lowest grid points in 0 s Calculated POLY solution 0 s, total time 0 s POLY:l-e OUTPUT TO SCREEN OR FILE /SCREEN/: Options /VWCS/: Output from POLY-3, equilibrium = 1, label A0 , database: SSOL4 Conditions: N=1, P=100000, T=973, W(SI)=7E-3, W(MG)=6E-3, W(MN)=4E-3 DEGREES OF FREEDOM 0 Temperature 973.00 K ( 699.85 C), Pressure 1.000000E+05 Number of moles of components 1.00000E+00, Mass in grams 2.70266E+01 Total Gibbs energy -4.14604E+04, Enthalpy 3.00566E+04, Volume 0.00000E+00 Component Moles W-Fraction Activity Potential Ref.stat AL 9.8462E-01 9.8300E-01 6.4349E-03 -4.0822E+04 SER MG 6.6719E-03 6.0000E-03 1.7894E-05 -8.8433E+04 SER MN 1.9678E-03 4.0000E-03 5.8523E-08 -1.3473E+05 SER SI 6.7362E-03 7.0000E-03 5.3450E-04 -6.0952E+04 SER LIQUID Status ENTERED Driving force 0.0000E+00 Moles 1.0000E+00, Mass 2.7027E+01, Volume fraction 0.0000E+00 Mass fractions: AL 9.83000E-01 SI 7.00000E-03 MG 6.00000E-03 MN 4.00000E-03 POLY:s-c T=873 POLY:c-e Using global minimization procedure Calculated 30111 grid points in 0 s Found the set of lowest grid points in 0 s Calculated POLY solution 0 s, total time 0 s POLY:l-e OUTPUT TO SCREEN OR FILE /SCREEN/: Options /VWCS/: Output from POLY-3, equilibrium = 1, label A0 , database: SSOL4 Conditions: N=1, P=100000, T=873, W(SI)=7E-3, W(MG)=6E-3, W(MN)=4E-3 DEGREES OF FREEDOM 0 Temperature 873.00 K ( 599.85 C), Pressure 1.000000E+05 Number of moles of components 1.00000E+00, Mass in grams 2.70266E+01 Total Gibbs energy -3.47879E+04, Enthalpy 1.62613E+04, Volume 0.00000E+00 Component Moles W-Fraction Activity Potential Ref.stat AL 9.8462E-01 9.8300E-01 8.7611E-03 -3.4387E+04 SER MG 6.6719E-03 6.0000E-03 7.7530E-05 -6.8701E+04 SER MN 1.9678E-03 4.0000E-03 2.2996E-08 -1.2766E+05 SER SI 6.7362E-03 7.0000E-03 1.1100E-02 -3.2669E+04 SER FCC_A1 Status ENTERED Driving force 0.0000E+00 Moles 9.9339E-01, Mass 2.6815E+01, Volume fraction 0.0000E+00 Mass fractions: AL 9.86052E-01 SI 6.22283E-03 MG 6.04727E-03 MN 1.67744E-03 ALMNSI_ALPHA Status ENTERED Driving force 0.0000E+00 Moles 6.6069E-03, Mass 2.1127E-01, Volume fraction 0.0000E+00 Mass fractions: AL 5.95561E-01 MN 2.98795E-01 SI 1.05644E-01 MG 0.00000E+00 POLY:s-c T=923 POLY:c-e Using global minimization procedure Calculated 30111 grid points in 0 s Found the set of lowest grid points in 0 s Calculated POLY solution 0 s, total time 0 s POLY:l-e OUTPUT TO SCREEN OR FILE /SCREEN/: Options /VWCS/: Output from POLY-3, equilibrium = 1, label A0 , database: SSOL4 Conditions: N=1, P=100000, T=923, W(SI)=7E-3, W(MG)=6E-3, W(MN)=4E-3 DEGREES OF FREEDOM 0 Temperature 923.00 K ( 649.85 C), Pressure 1.000000E+05 Number of moles of components 1.00000E+00, Mass in grams 2.70266E+01 Total Gibbs energy -3.78334E+04, Enthalpy 2.47271E+04, Volume 0.00000E+00 Component Moles W-Fraction Activity Potential Ref.stat AL 9.8462E-01 9.8300E-01 7.7863E-03 -3.7262E+04 SER MG 6.6719E-03 6.0000E-03 2.6414E-05 -8.0899E+04 SER MN 1.9678E-03 4.0000E-03 5.2149E-08 -1.2869E+05 SER SI 6.7362E-03 7.0000E-03 1.1109E-03 -5.2205E+04 SER LIQUID Status ENTERED Driving force 0.0000E+00 Moles 6.4828E-01, Mass 1.7525E+01, Volume fraction 0.0000E+00 Mass fractions: AL 9.77223E-01 SI 1.02577E-02 MG 7.92906E-03 MN 4.59033E-03 FCC_A1 Status ENTERED Driving force 0.0000E+00 Moles 3.5172E-01, Mass 9.5021E+00, Volume fraction 0.0000E+00 Mass fractions: AL 9.93655E-01 MN 2.91126E-03 MG 2.44227E-03 SI 9.91803E-04 POLY:change For phases, species or components? /PHASES/: Phase name(s):liq Status: /ENTERED/: Start value, number of mole formula units /0/: POLY:s-c T=none POLY:c-e *** ERROR 2003 IN QMJBSV: Degrees of freedom not zero POLY:c-e *** ERROR 2003 IN QMJBSV: Degrees of freedom not zero POLY:l-c N=1, P=100000, W(SI)=7E-3, W(MG)=6E-3, W(MN)=4E-3 DEGREES OF FREEDOM 1 POLY:chang For phases, species or components? /PHASES/: Phase name(s):liquid Status: /ENTERED/:fix Number of mole formula units /0/: POLY:l-c N=1, P=100000, W(SI)=7E-3, W(MG)=6E-3, W(MN)=4E-3 FIXED PHASES LIQUID=0 DEGREES OF FREEDOM 0 POLY:c-e Normal POLY minimization, not global Testing POLY result by global minimization procedure Calculated 30111 grid points in 0 s 22 ITS, CPU TIME USED 0 SECONDS POLY:l-e OUTPUT TO SCREEN OR FILE /SCREEN/: Options /VWCS/: Output from POLY-3, equilibrium = 1, label A0 , database: SSOL4 Conditions: N=1, P=100000, W(SI)=7E-3, W(MG)=6E-3, W(MN)=4E-3 FIXED PHASES LIQUID=0 DEGREES OF FREEDOM 0 Temperature 880.93 K ( 607.78 C), Pressure 1.000000E+05 Number of moles of components 1.00000E+00, Mass in grams 2.70266E+01 Total Gibbs energy -3.52529E+04, Enthalpy 1.65310E+04, Volume 0.00000E+00 Component Moles W-Fraction Activity Potential Ref.stat AL 9.8462E-01 9.8300E-01 8.5846E-03 -3.4848E+04 SER MG 6.6719E-03 6.0000E-03 7.5162E-05 -6.9553E+04 SER MN 1.9678E-03 4.0000E-03 2.7371E-08 -1.2755E+05 SER SI 6.7362E-03 7.0000E-03 1.0407E-02 -3.3438E+04 SER FCC_A1 Status ENTERED Driving force 0.0000E+00 Moles 9.9404E-01, Mass 2.6836E+01, Volume fraction 0.0000E+00 Mass fractions: AL 9.85749E-01 SI 6.30134E-03 MG 6.04261E-03 MN 1.90669E-03 ALMNSI_ALPHA Status ENTERED Driving force 0.0000E+00 Moles 5.9594E-03, Mass 1.9056E-01, Volume fraction 0.0000E+00 Mass fractions: AL 5.95811E-01 MN 2.98798E-01 SI 1.05391E-01 MG 0.00000E+00 LIQUID Status FIXED Driving force 0.0000E+00 Moles 0.0000E+00, Mass 0.0000E+00, Volume fraction 0.0000E+00 Mass fractions: AL 9.01166E-01 SI 6.68278E-02 MG 2.77785E-02 MN 4.22729E-03 POLY:ch For phases, species or components? /PHASES/: Phase name(s): *** ERROR 1032 IN GPAR : PARAMETER VALUE MISSING POLY: POLY: POLY: POLY:ch For phases, species or components? /PHASES/: Phase name(s):liq Status: /ENTERED/:fix Number of mole formula units /0/:1 POLY: POLY:c-ew Ambiguous command, use ? POLY:c-e Normal POLY minimization, not global Testing POLY result by global minimization procedure Calculated 30111 grid points in 0 s 19 ITS, CPU TIME USED 0 SECONDS POLY:l-e OUTPUT TO SCREEN OR FILE /SCREEN/: Options /VWCS/: Output from POLY-3, equilibrium = 1, label A0 , database: SSOL4 Conditions: N=1, P=100000, W(SI)=7E-3, W(MG)=6E-3, W(MN)=4E-3 FIXED PHASES LIQUID=1 DEGREES OF FREEDOM 0 Temperature 925.91 K ( 652.76 C), Pressure 1.000000E+05 Number of moles of components 1.00000E+00, Mass in grams 2.70266E+01 Total Gibbs energy -3.80358E+04, Enthalpy 2.85624E+04, Volume 0.00000E+00 Component Moles W-Fraction Activity Potential Ref.stat AL 9.8462E-01 9.8300E-01 7.7383E-03 -3.7427E+04 SER MG 6.6719E-03 6.0000E-03 2.0132E-05 -8.3245E+04 SER MN 1.9678E-03 4.0000E-03 4.6406E-08 -1.3000E+05 SER SI 6.7362E-03 7.0000E-03 7.4703E-04 -5.5424E+04 SER LIQUID Status FIXED Driving force 0.0000E+00 Moles 1.0000E+00, Mass 2.7027E+01, Volume fraction 0.0000E+00 Mass fractions: AL 9.83000E-01 SI 7.00000E-03 MG 6.00000E-03 MN 4.00000E-03 FCC_A1 Status ENTERED Driving force 0.0000E+00 Moles 0.0000E+00, Mass 0.0000E+00, Volume fraction 0.0000E+00 Mass fractions: AL 9.94866E-01 MN 2.56862E-03 MG 1.88241E-03 SI 6.82988E-04 POLY:ch For phases, species or components? /PHASES/: Phase name(s):liq Status: /ENTERED/: Start value, number of mole formula units /0/: POLY: POLY:s-c T=900 POLY:c-e Using global minimization procedure Calculated 30111 grid points in 0 s Found the set of lowest grid points in 0 s Calculated POLY solution 0 s, total time 0 s POLY:l-e OUTPUT TO SCREEN OR FILE /SCREEN/: Options /VWCS/: Output from POLY-3, equilibrium = 1, label A0 , database: SSOL4 Conditions: N=1, P=100000, T=900, W(SI)=7E-3, W(MG)=6E-3, W(MN)=4E-3 DEGREES OF FREEDOM 0 Temperature 900.00 K ( 626.85 C), Pressure 1.000000E+05 Number of moles of components 1.00000E+00, Mass in grams 2.70266E+01 Total Gibbs energy -3.63883E+04, Enthalpy 1.80626E+04, Volume 0.00000E+00 Component Moles W-Fraction Activity Potential Ref.stat AL 9.8462E-01 9.8300E-01 8.2032E-03 -3.5943E+04 SER MG 6.6719E-03 6.0000E-03 5.6729E-05 -7.3164E+04 SER MN 1.9678E-03 4.0000E-03 5.7714E-08 -1.2473E+05 SER SI 6.7362E-03 7.0000E-03 5.2651E-03 -3.9261E+04 SER FCC_A1 Status ENTERED Driving force 0.0000E+00 Moles 9.1506E-01, Mass 2.4726E+01, Volume fraction 0.0000E+00 Mass fractions: AL 9.87749E-01 MG 4.82898E-03 SI 3.83466E-03 MN 3.58764E-03 LIQUID Status ENTERED Driving force 0.0000E+00 Moles 8.4529E-02, Mass 2.2876E+00, Volume fraction 0.0000E+00 Mass fractions: AL 9.33864E-01 SI 4.06826E-02 MG 1.86918E-02 MN 6.76143E-03 ALMNSI_ALPHA Status ENTERED Driving force 0.0000E+00 Moles 4.1149E-04, Mass 1.3155E-02, Volume fraction 0.0000E+00 Mass fractions: AL 6.01844E-01 MN 2.98870E-01 SI 9.92859E-02 MG 0.00000E+00 POLY:s-a-v Axis number: /1/: Condition /NONE/:T Min value /0/:850 Max value /1/:1000 Increment /3.75/: POLY:step Option? /NORMAL/: No initial equilibrium, using default Step will start from axis value 900.000 ...OK Phase Region from 900.000 for: LIQUID ALMNSI_ALPHA FCC_A1 Global check of removing phase at 9.00852E+02 Calculated 3 equilibria Phase Region from 900.852 for: LIQUID FCC_A1 Global check of removing phase at 9.25907E+02 Calculated 9 equilibria Phase Region from 925.907 for: LIQUID Global test at 9.52500E+02 .... OK Global test at 9.90000E+02 .... OK Terminating at 1000.00 Calculated 24 equilibria Phase Region from 900.000 for: LIQUID ALMNSI_ALPHA FCC_A1 Global check of removing phase at 8.80932E+02 Calculated 8 equilibria Phase Region from 880.932 for: ALMNSI_ALPHA FCC_A1 Global test at 8.51250E+02 .... OK Terminating at 850.000 Calculated 12 equilibria *** Buffer saved on file: C:\Users\Dozent\AppData\Local\Temp\RESULT_001.POLY3 POLY:post POLY-3 POSTPROCESSOR VERSION 3.2 Setting automatic diagram axes POST:s-d-a AXIS (X, Y OR Z) :x VARIABLE :T_C POST:s-d-a AXIS (X, Y OR Z) :y VARIABLE :npm(liq) POST:plot POST: POST:s-d-a AXIS (X, Y OR Z) :y VARIABLE :vpv(liq) POST:plot POST: POST:s-d-a AXIS (X, Y OR Z) :y VARIABLE :npm(liq) POST:plot POST: POST:s-s-s AXIS (X, Y OR Z) :y AUTOMATIC SCALING (Y OR N) /N/: MIN VALUE :-0.05 MAX VALUE :1.05 POST:plot POST: POST: